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A Trinuclear Heterobimetallic Ru(II)/Pt(II) Complex as a Chemodosimeter Selective for Sulfhydryl-Containing Amino Acids and Peptides
135
Citations
29
References
2003
Year
Inorganic ChemistryBiochemistryNatural SciencesCoordination ComplexMolecular SwitchSulfhydryl-containing Amino AcidsLuminescent ChemodosimeterPeptide ScienceMolecular ComplexTrinuclear Heterobimetallic RuChemistryChemodosimeter SelectiveInorganic Compound
A trinuclear heterobimetallic Ru(II)/Pt(II) complex, cis-{Ru(phen)2[CN-Pt(DMSO)Cl2]2} (phen = 1,10-phenanthroline), is able to function as a "switch-on" luminescent chemodosimeter for sulfhydryl-containing amino acids and peptides via specific binding of the amino acids/peptides with the Pt(II) centers and the subsequent cleavage of the Ru(II)-Pt(II) cyano-bridge.
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