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α-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn<sup>III</sup><sub>9</sub>Complex
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2010
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Materials ScienceInorganic ChemistryMagnetismSpintronicsMagnetic StudyAlpha-benzoin OximeEngineeringCluster ScienceCoordination ComplexNew Enneanuclear MnMagnetic Resonanceα-Benzoin OximeMetal Cluster ChemistryCluster ChemistryChemistryCrystallographyInorganic SynthesisInorganic Compound
The initial employment of alpha-benzoin oxime (bzoxH(2)) in higher oxidation state 3d metal cluster chemistry has provided access to a new enneanuclear Mn(III) complex with an unprecedented metal-core topology consisting of two triangular [Mn(3)(mu(3)-Omicron(2-))(mu-OmicronNu)(3)](4+) fragments connected by a linear [Mn(3)(mu-OmicronNu)(6)](3+) unit. The Mn(III)(9) cluster is antiferromagnetically coupled and has an S = 3 spin ground state.