An Efficient and General Iron‐Catalyzed Arylation of Benzyl Alcohols and Benzyl Carboxylates

I. Iovel, Kristin Mertins, Jette Kischel, Alexander Zapf, Matthias Beller

Angewandte Chemie International Edition · 2005 · 354 citations · 58 references

Concepts

Abstract

Green grow the diarylmethanes: Substituted arenes and heteroarenes can be easily benzylated in the presence of inexpensive and relatively nontoxic metal salts such as FeCl3 (see scheme). This arylation method with benzyl alcohols is a state-of-the-art green route to diarylmethanes as water is the only by-product.

References

58