Angewandte Chemie International Edition · 2005 · 354 citations · 58 references
Chemical EngineeringNovel OrganocatalystsEngineeringState-of-the-art Green RouteHeterocyclicArylation MethodBenzyl CarboxylatesGreen ChemistrySustainable SynthesisOrganic ChemistryCatalysisGeneral Iron‐catalyzed ArylationChemistryHomogeneous CatalysisMolecular CatalysisBenzyl AlcoholsCatalytic SynthesisGreen Methodology
Green grow the diarylmethanes: Substituted arenes and heteroarenes can be easily benzylated in the presence of inexpensive and relatively nontoxic metal salts such as FeCl3 (see scheme). This arylation method with benzyl alcohols is a state-of-the-art green route to diarylmethanes as water is the only by-product.
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Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins
Shinji Murai, Fumitoshi Kakiuchi, Shinya Sekine et al. · Nature · 1993 · 1.4K citations
Fumitoshi Kakiuchi, Shinji Murai · Accounts of Chemical Research · 2002 · 1.1K citations