<i>Ab initio</i>potential energy curves for SH

Abstract

Ab initio MRD CI calculations are presented for the states of SH correlating with H(2 S) + S(3 P, 1 D, 1 S). Only the X 2Π and A 2Σ+ states are bound. On the basis of vertical excitation calculations it is suggested that the B 2Σ state is 2Σ-.