Magnetic Properties of Dysprosium Cubanes Dictated by the M−O−M Angles of the [Dy₄(μ₃-OH)₄] Core

Abstract

Two new dysprosium(III) coordination compounds, namely, [Dy(4)(HL)(4)(C(6)H(4)NH(2)COO)(2)(mu(3)-OH)(4)(mu-OH)(2)(H(2)O)(4)].4CH(3)CN.12H(2)O (1) and Dy(8)(HL)(10)(C(6)H(4)NH(2)COO)(2)(mu(3)-OH)(8)(OH)(2)(NO(3))(2)(H(2)O)(4)] (2), have been synthesized from the Schiff-base ligand 2-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoic acid (H(2)L) and dysprosium chloride (1) or dysprosium nitrate (2). Single-crystal X-ray diffraction studies reveal that compound 1 exhibits a tetranuclear cubane-like structure and that 2 is an octanuclear, bis-cubane complex. The [Dy(4)(mu (3)-OH)(4)] cubane cores of 1 and 2 are structurally related; however, the magnetic properties of 1 and 2 are drastically different. Indeed, 2 shows slow relaxation of magnetization while no out-of-phase alternating current (ac) signal is noticed for 1. These significant disparities are most likely due to the different M-O-M angles observed for the respective cubane cores.