Concepedia

Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions

Xiaodan Zhao, Zhengkun Yu

Journal of the American Chemical Society · 2008 · 195 citations · 34 references

DOI

Concepts

Abstract

Efficient rhodium(I)-catalyzed regioselective functionalization of aromatic C-H bonds has been realized with acid chlorides as the coupling partners via decarbonylation and C-H activation under phosphine-free conditions.

References

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Catalytic Intermolecular Direct Arylation of Perfluorobenzenes

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Palladium-Catalyzed Methylation and Arylation of sp<sup>2</sup> and sp<sup>3</sup> C−H Bonds in Simple Carboxylic Acids

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An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage:  Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air

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