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Chiral [(Dialkylamino)methyl](phospholyl)ferrocene Ligands as a New Class of 1,2‐Disubstituted Ferrocene Ligands
31
Citations
65
References
2003
Year
Ferrocene LigandsInorganic ChemistryAsymmetric CatalysisEngineeringNatural SciencesCoordination ComplexDiversity-oriented SynthesisOrganic ChemistryNew ClassOrganometallic CatalysisCatalysisEfficient SynthesisChemistryStereoselective SynthesisNew Chiral NPure FormEnantioselective SynthesisBiomolecular Engineering
Abstract An efficient synthesis of new chiral [(dialkylamino)methyl](phospholyl)ferrocenes in an enantiomerically pure form has been developed. These new chiral N,P ligands have been tested in the palladium‐catalyzed allylic substitution reaction. High activities and moderate enantioselectivities (up to 67% ee ) were observed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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