A Study of Oil Displacement by Microemulsion Systems – Mechanisms and Phase Behavior

Abstract

Abstract Microemulsions located in a narrow single-phase region on the phase diagram for the quaternary system consisting of nonane, isopropyl alcohol, Witco TRS 10-80 petroleum sulfonate, and brine were used to investigate the effect of phase behavior on displacement efficiency of the micellar flooding process. Microemulsion floods were conducted at reservoir rates in 4-ft (1.22-m) Berea cores containing brine and residual nonane. Two floods were made using large (1.0-PV) slugs. A third flood used a 0.1-PV slug followed by a mobility buffer of polyacrylamide. Extensive analyses of the core effluents were made for water, nonane, alcohol, and mono- and polysulfonates. An oil bank developed which broke through at 0.08 to 0.1 PV, and 48 to 70% of the oil was recovered in this bank which preceeded breakthrough of monosulfonate and alcohol. Coincidental with the arrival of these components of the slug, the effluent became a milky white macroemulsion which partially separated upon standing. Additional oil was recovered with the macroemulsion. Ultimate recoveries were 90 to 100% of the residual oil. Low apparent interfacial tension was observed between the emulsion and nonane. Alcohol arrived in the effluent at the same time as monosulfonate even though there was extensive adsorption of the sulfonate. Further, alcohol appeared in the effluent well after sulfonate production had ceased, indicating retention of the alcohol in the core. A qualitative model describing the displacement process was inferred from the appearance of the produced fluids and the analyses of the effluents.