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UNEQUIVOCAL SYNTHESIS OF PHENACYLIDENEANILINE FROM SILYL ENOL ETHERS AND NITROSOBENZENE AND ONE-POT CYCLOADDITION REACTIONS OF THE RELATED ANILS

DOI

22

Citations

1

References

1983

Year

Tadashi Sasaki, Yukio Ishibashi, Masatomi Ohno
Chemistry Letters

Abstract

Abstract Phenacylideneaniline was formed by Et3N-catalyzed elimination reaction of the hydroxylamine obtained from silyl enol ether 5a and nitrosobenzene (6). By this method, one-pot procedure was possible for cycloaddition reactions of the related anils. From these reactions, it was revealed that 6 reacted efficiently with a silyl enol ether having a π-donating substituent.

References

YearCitations

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