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In the presence of very fast comproportionation, sampled current voltammetry and rotating disk electrode voltammetry yield equal two versus one-electron limiting current ratios. Reconciliation through analysis of concentration profiles

Chemical EngineeringElectrical EngineeringConcentration ProfilesEngineeringElectrochemical InterfaceCurrent RatiosElectrochemical CellEqual TwoElectrode Reaction MechanismElectrochemistry