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The first hexacarboxylato diruthenium(<scp>III</scp>) complex. Synthesis, X-ray crystal structure, and properties of tetra-µ-acetato-diacetatodiruthenium(<scp>III</scp>) monohydrate
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1987
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X-ray CrystallographyEngineeringOrganic ChemistryChemistryInorganic CompoundStructure ElucidationX-ray Crystal StructureRedox ChemistryMaterials ScienceInorganic ChemistryFirst Hexacarboxylato DirutheniumCrystallographyInorganic SynthesisBiomolecular EngineeringParamagnetic Ru26+ ComplexNatural SciencesCoordination ComplexMolecular ComplexFirst Example
The reaction of [Ru2(µ-OAc)4Cl] with AgOAc in AcOH/MeOH gives the red oxidation product [Ru2(µ-OAc)4(OAc)2]·H2O (1), the structure of which has been determined by X-ray crystallography; this is the first example of a paramagnetic Ru26+ complex.