Cellulose acetate and sulfonated polysulfone blend ultrafiltration membranes. I. Preparation and characterization

Abstract

Abstract Modification of polymeric membrane materials by incorporation of hydrophilicity results in membranes with low fouling behavior and high flux. Hence, Polysulfone was functionalized by sulfonation and ultrafiltration membranes were prepared based on sulfonated polysulfone and cellulose acetate in various blend compositions. Polyethyleneglycol 600 was employed as a nonsolvent additive in various concentrations to the casting solution to improve the ultrafiltration performance of the resulting membranes. The total polymer concentration, cellulose acetate, and sulfonated polysulfone polymer blend composition, additive concentration, and its compatibility with polymer blends were optimized. The membranes prepared were characterized in terms of compaction, pure water flux, membrane resistance, and water content. The compaction takes place within 3–4 h for all the membranes. The pure water flux is determined largely by the composition of sulfonated polysulfone and concentration of additive. Membrane resistance is inversely proportional to pure water flux, and water content is proportional to pure water flux for all the membranes. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1749–1761, 2002