Publication | Closed Access
Molecular Design of a Calix[6]arene-Based Super-Uranophile with C3 Symmetry. High UO22+ Selectivity in Solvent Extraction
41
Citations
5
References
1993
Year
Excellent Selectivity FactorsSolvent ExtractionChemical EngineeringNovel OrganocatalystsEngineeringOrganic ChemistryHigh Uo22+ SelectivityOrganometallic CatalysisCatalysisMain Group ChemistryChemistryC3 SymmetryDeep Eutectic SolventInorganic SynthesisBiomolecular EngineeringInorganic Compound
Abstract Calix[6]arene bearing three carboxylate groups arranged in C3 symmetry formed a 1 : 1 complex with UO22+ and showed much more excellent selectivity factors for UO22+ in solvent extraction than calix[6]arene bearing six carboxylate groups. This establishes that the essence of “super-uranophiles” is related to the molecular design of C3 symmetry.
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