Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M<sub>2</sub>(C<sub>2</sub>)<sup>+</sup>˙; M = cyclic(alkyl)(amino)carbene] - Concepedia

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Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M<sub>2</sub>(C<sub>2</sub>)<sup>+</sup>˙; M = cyclic(alkyl)(amino)carbene]

92

Citations

47

References

2014

Year

Liqun Jin, Mohand Melaïmi, Liu Leo Liu, Guy Bertrand

Organic Chemistry Frontiers

Materials ScienceOrganic Material ChemistryChemical EngineeringEngineeringAlkene MetathesisSinglet CarbenesRadical (Chemistry)Transition MetalsOrganic ChemistryReactivity (Chemistry)Organometallic CatalysisCatalysisChemistry

Abstract

A bis-carbene-stabilized ethynyl radical cation, a purely organic mixed valence compound, is indefinitely air stable.

References

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