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Highly Diastereoselective Michael Addition Reactions of Lithium Enolates to Ethyl 3-Trifluoromethylacrylate
27
Citations
8
References
1991
Year
EngineeringLithium EnolatesExcellent Chemical YieldsOrganic ChemistryCarbon–carbon BondCatalysisChemistryHalogenationAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract Michael addition reactions of lithium enolates derived from ketones, esters, and amides to ethyl 3-trifluoromethylacrylate were found to proceed smoothly in moderate to excellent chemical yields as well as with a high degree of diastereoselectivity at the newly formed carbon–carbon bond.
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