Chemistry Letters · 1999 · 64 citations · 9 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalyst PreparationCatalyst SynthesisCatalytic MechanismsHeterocycle SynthesisOrganic SynthesisOxidation ReactionsArylation ReactionsOrganometallic CatalysisPalladium Catalysts
Abstract Phenols undergo pentaarylation around the oxygen upon a single treatment with excess aryl bromides in the presence of a palladium catalyst system to produce 2-(1,1′-biphenyl-2-yl)-6-(1,1′:3′,1″-terphenyl-2′-yl)phenol derivatives.
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Grace Mann, Christopher D. Incarvito, Arnold L. Rheingold et al. · Journal of the American Chemical Society · 1999 · 443 citations