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The Wittig rearrangement of some allyl ethers
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1970
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Cross-coupling ReactionEngineeringAlkene MetathesisCyclic MechanismWittig RearrangementOrganic ChemistryAllyl EthersStereoselective SynthesisChemistryAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
The products and stereochemistry in the Wittig rearrangement of some allyl ethers are in accord with a highly ordered cyclic mechanism; dissociation and recombination can significantly compete with this process.