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A Transition Metal Atom as Building Block of a Cyclic Phosphazene– Synthesis and Structure of [Cl<sub>3</sub>WN<sub>3</sub>(PPh<sub>2</sub>)<sub>2</sub>]
51
Citations
3
References
1986
Year
Materials ScienceInorganic ChemistryEngineeringBuilding BlockCyclic Phosphazene– SynthesisTungsten Hexachloride 1Organic ChemistryTitle Compound 3Main Group ChemistryYellow Phosphazene 3ChemistryCoordination PolymerOrganometallic PolymerCrystallographyTransition Metal AtomInorganic SynthesisInorganic Compound
A six-membered planar WN3P2 ring characterizes the structure of the title compound 3; probably a chlorine-bridged polymer is present in the solid state. The yellow phosphazene 3 is formed upon reaction of tungsten hexachloride 1 with the salt 2 in chloroform.
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