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Self-Organization of a Heteroditopic Molecule to Linear Polymolecular Arrays in Solution
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1998
Year
Heteroditopic Self-complementary MoleculeSupramolecular AssemblyEngineeringNatural SciencesMolecular Self-assemblySelf-assemblyPolymolecular ArraysMolecular BiologyOrganic ChemistryHeteroditopic MoleculeCrown Ether UnitChemistryMolecular EngineeringParaquat UnitMacromolecular ArchitectureBiophysicsPolymers
Like the proverbial monkey chain one heteroditopic self-complementary molecule, comprising a crown ether unit and a paraquat unit, catches a second such molecule in solution and thus by self-organization forms novel linear oligo- and polymolecular arrays (shown schematically; the crown ether unit is denoted by the ellipse, and the paraquat unit by the rectangle).