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Metallosupramolecular Thin Polyelectrolyte Films
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1998
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Materials ScienceMolecular RecognitionChemical EngineeringConducting PolymerEngineeringPolymer SciencePolyelectrolyte GelNanostructured PolymerInorganic PolymerChemistryMolecular EngineeringThin FilmsPss LayersElectrostatic InteractionSupramolecular PolymerPolymer Chemistry
Molecular recognition and electrostatic interaction of oppositely charged polyelectrolytes are combined in the fabrication of ultrathin metallosupramolecular multilayers [shown schematically in the picture, PEI=polyethyleneimine, PSS=poly(styrene sulfonate)]. The layers between the PSS layers are composed of an iron(II) bis(terpyridine) coordination polymer.