Journal of Materials Chemistry · 2011 · 105 citations · 10 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistrySolid State PhysicsSolid-state ChemistryCrystal ChemistryDefects In Electronic MaterialsElectrolyte MaterialsLanthanide ChemistrySolid-state ElectrolytesStrongly Correlated Electron SystemsConductionIntrinsic DefectsLanthanide Electronic StructureLanthanide HydridesLanthanide OxidesProton ConductionSolid Electrolyte SynthesisTungsten-based Materials
This is the first paper reporting that lanthanum tungstate, earlier believed to be La6WO12, is in fact La28−xW4+xO54+δ , where tungsten dissolves in lanthanum sites to form a stable solid-state electrolyte, exhibiting proton conduction by hydration at intermediate temperatures.
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