Concepedia

Synthesis of Ruthenium(II) 1,2,3-Trimethylindenyl Complexes:  X-ray Crystal Structure of [Ru(CCCPh<sub>2</sub>)(η<sup>5</sup>-1,2,3-Me<sub>3</sub>C<sub>9</sub>H<sub>4</sub>)(CO)(PPh<sub>3</sub>)][BF<sub>4</sub>]

M. Pilar Gamasa, José Gimeno, Covadonga González-Bernardo, Javier Borge, Santiago García‐Granda

Organometallics · 1997 · 64 citations · 17 references

DOI

Concepts

Abstract

The first ruthenium(II) 1,2,3-trimethylindenyl complexes have been prepared, including allenylidene, alkynyl, and alkenylcarbene derivatives. The X-ray crystal structure of [Ru( C C CPh 2 )(η 5 -1,2,3-Me 3 C 9 H 4 )(CO)(PPh 3 )] [BF 4 ] is described.

References

17

Synthesis and structure of [Ru(C3Ph2)(PMe3)2(Cp)][PF6], a cationic diphenylallenylidene complex

John P. Selegue · Organometallics · 1982 · 273 citations

, , +7

Activation of 2-Propyn-1-ol Derivatives by Indenylruthenium(II) and -osmium(II) Complexes:  X-ray Crystal Structures of the Allenylidene Complexes [M(CCCPh<sub>2</sub>)(η<sup>5</sup>-C<sub>9</sub>H<sub>7</sub>)(PPh<sub>3</sub>)<sub>2</sub>][PF<sub>6</sub>]·CH<sub>2</sub>Cl<sub>2</sub> (M = Ru, Os) and EHMO Calculations

Victorio Cadierno, M. Pilar Gamasa, José Gimeno et al. · Organometallics · 1996 · 168 citations

, , +17

Activation of 2-propyn-1-ol derivatives by (arene)ruthenium(II) complexes: new route to (alkenylcarbene)- and (polyenylcarbene)-metal complexes

Didier Pilette, Khalid Ouzzine, Hubert Le Bozec et al. · Organometallics · 1992 · 142 citations

, , +9

Alkyl-substituted indenyl titanium precursors for syndiospecific ziegler-natta polymerization of styrene

Thomas E. Ready, James C. W. Chien, Marvin D. Rausch · Journal of Organometallic Chemistry · 1996 · 117 citations

, , +11

Structural characterization of alkyne and vinylidene isomers of [Ru(C2H2)(PMe2Ph)2(Cp)][BF4]

Jeffrey R. Lomprey, John P. Selegue · Journal of the American Chemical Society · 1992 · 97 citations

, , +6