Science · 1994 · 239 citations · 39 references
Natural SciencesEarth SciencesMeteorologyAtmospheric ChemistryAtmospheric ScienceCloud PhysicsAtmospheric Boundary LayerAtmospheric Oxidation ProcessesNitrogen OxidesPlanetary Boundary LayerStratospheric ChemistryTropospheric ChemistryAtmospheric Oxidation MechanismsChemical Destruction PathwaysConvective OverturningNitrogen DioxideOzoneOzone BudgetOzone DynamicsTropospheric Ozone Chemistry
Convective updrafts in thunderstorms prolong the lifetime of ozone (O(3)) and its anthropogenic precursor NOx [nitric oxide (NO) + nitrogen dioxide (NO(2))] by carrying these gases rapidly upward from the boundary layer into a regime where the O(3) production efficiency is higher, chemical destruction is slower, and surface deposition is absent. On the other hand, the upper troposphere is relatively rich in O(3) and NOx from natural sources such as downward transport from the stratosphere and lightning; convective overturning conveys the O(3) and NOx toward the Earth's surface where these components are more efficiently removed from the atmosphere. Simulations with a three-dimensional global model suggest that the net result of these counteractive processes is a 20 percent overall reduction in total tropospheric O(3). However, the net atmospheric oxidation efficiency is enhanced by 10 to 20 percent.
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