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Studies on gold(II) complexes with hard and soft donor ligands. Part I. Complexes with o-aminobenzenethiol
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1988
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Binuclear GoldInorganic ChemistrySoft Donor LigandsEngineeringBiochemistrySeven-line E.s.rNatural SciencesCoordination ComplexMolecular ComplexSulphur DonorsChemistryPart I. ComplexesInorganic SynthesisBiomolecular EngineeringInorganic Compound
The synthesis and characterisation of gold(II) complexes with o-aminobenzenethiol is reported. The e.s.r. results indicate that the highest occupied molecular orbital has appreciable contribution from the sulphur donors of the ligands. It is the first time that binuclear gold(II) complexes giving well resolved seven-line e.s.r. patterns originating from two 197Au nuclei have been reported.