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The Role of Colloid Formation in the Photoinduced H<sub>2</sub> Production with a Ru<sup>II</sup>−Pd<sup>II</sup> Supramolecular Complex: A Study by GC, XPS, and TEM
172
Citations
7
References
2007
Year
Inorganic ChemistryChemical EngineeringColloid FormationEngineeringPhotoredox ProcessPhotochemistryDinuclear Ruii-pdii ComplexMechanistic PhotochemistryH2 ProductionInorganic PhotochemistryPhotocatalysisCatalysisHydrogenChemistryProton DonorSupramolecular PhotochemistryHydrogen Generation
The dinuclear RuII-PdII complex shows efficient H2 production in the presence of triethylamine as a sacrificial electron and proton donor under visible light irradiation. XPS and TEM analyses reveal that photoreduction of PdII to Pd0 causes dissociation of Pd from the complex to form colloids that are suggested to be the actual catalyst for H2 production.
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