Concepedia

Syntheses, Structures and Magnetic Behaviors of Di- and Trinuclear Pivalate Complexes Containing Both Cobalt(II) and Lanthanide(III) Ions

Yong Cui, Gang Chen, Jin Ren, Yitai Qian, Jin‐Shun Huang

Inorganic Chemistry · 2000 · 41 citations · 23 references

DOI

Concepts

Abstract

The syntheses and X-ray structures of the di- and trinuclear pivalates [C9H7NH][CoTb(Piv)3(C9H7N)(NO3)3]·0.5H2O, [CoLn(Piv)5(C9H7N)(H2O)]·0.5C9H7N (Ln = Gd, Dy), and [Co2Gd(Piv)6(C9H7N)2(NO3)] (Piv = O2CCMe3) are reported. The four complexes all exhibit weak ferromagnetic interactions between their corresponding heterometallic ions.

References

23

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Crystal structure and magnetic properties of [Ln2Cu4] hexanuclear clusters (where Ln = trivalent lanthanide). Mechanism of the gadolinium(III)-copper(II) magnetic interaction

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Design and Magnetic Properties of a Magnetically Isolated Gd<sup>III</sup>Cu<sup>II</sup> Pair. Crystal Structures of [Gd(hfa)<sub>3</sub>Cu(salen)], [Y(hfa)<sub>3</sub>Cu(salen)], [Gd(hfa)<sub>3</sub>Cu(salen)(Meim)], and [La(hfa)<sub>3</sub>(H<sub>2</sub>O)Cu(salen)] [hfa = Hexafluoroacetylacetonato, salen = <i>N</i>,<i>N</i>‘-Ethylenebis(salicylideneaminato), Meim = 1-Methylimidazole]

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Nature of the Interaction between Ln<sup>III</sup> and Cu<sup>II</sup> Ions in the Ladder-Type Compounds {Ln<sub>2</sub>[Cu(opba)]<sub>3</sub>}·S (Ln = Lanthanide Element; opba = <i>ortho</i>-Phenylenebis(oxamato), S = Solvent Molecules)

Myrtil L. Kahn, Corine Mathonière, Olivier Kahn · Inorganic Chemistry · 1999 · 259 citations

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A Genuine Example of a Discrete Bimetallic (Cu, Gd) Complex:  Structural Determination and Magnetic Properties

Jean‐Pierre Costes, Françoise Dahan, Arnaud Dupuis et al. · Inorganic Chemistry · 1996 · 257 citations

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