Equation-of-state data for molecular hydrogen and deuterium at shock pressures in the range 2–76 GPa (20–760 kbar)a)

Abstract

Dynamic equation-of-state data for D2 and H2 were measured in the pressure range 2–76 GPa (20–760 kbar) using a two-state light-gas gun. Liquid specimens were shocked from initial states near the saturation curve at 20 K. Maximum compression was sixfold over initial liquid density at a calculated temperature of 7000 K for D2. The data is discussed in terms of the theory of Ross et al., which includes an effective intermolecular pair potential, molecular vibration, free molecular rotation, and molecular dissociation.