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Silver‐Tellurolate Polynuclear Complexes: From Isolated Cluster Units to Extended Polymer Chains
57
Citations
8
References
1997
Year
Reagent TeEngineeringChemistryLinear Chain CompoundPolymersMacromolecular EngineeringSilver‐tellurolate Polynuclear ComplexesTertiary PhosphanesPolymer ChemistryInorganic ChemistryIsolated Cluster UnitsBiomolecular EngineeringExtended Polymer ChainsIntracluster BridgesCoordination ComplexPolymer ScienceMolecular ComplexCoordination PolymerPolymer Synthesis
In the presence of tertiary phosphanes, AgCl reacts readily with the reagent Te(Ph)SiMe3 to yield silver-tellurolate polynuclear complexes. In the case of PMe3, the polymer [Ag10(μ3-TePh)10(PMe3)2]∞ (shown below) is formed, in which the TePh ligands serve as both inter- and intracluster bridges.
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