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Switching of two amine ligands via an S<sub>N</sub>2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates
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Citations
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References
1995
Year
Combinatorial ChemistryInorganic ChemistryFacile ExchangeSolid PhaseEngineeringAmine LigandsBiochemistryNmr SpectroscopyCoordinated FormNatural SciencesCoordination ComplexMolecular SwitchOrganic ChemistryMolecular ComplexChemistryHeterocycle ChemistryBiomolecular Engineering
Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.
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