Concepedia

Switching of two amine ligands via an S<sub>N</sub>2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

Shinji Toyota, Tadahiro Futawaka, Hiroshi Ikeda, Michinori Ōki

Journal of the Chemical Society Chemical Communications · 1995 · 38 citations · 13 references

DOI

Concepts

Abstract

Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.

References

13

Comparative Theoretical Study of Lewis Acid-Base Complexes of BH3, BF3, BCl3, AlCl3, and SO2

Volker Jonas, Gernot Frenking, Manfred T. Reetz · Journal of the American Chemical Society · 1994 · 460 citations

, , +9

Applications of Dynamic NMR Spectroscopy to Organic Chemistry,

Bruce Coxon · Carbohydrate Research · 1986 · 265 citations

, , +9

Trans-2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of palladium(II) and platinum(II). Crystal structure of [PtI[MeC6H3(CH2NMe2)2-o,o']]BF4: a cyclohexadienyl carbonium ion with a .sigma.-bonded metal substituent

David M. Grove, Gerard van Koten, Jaap N. Louwen et al. · Journal of the American Chemical Society · 1982 · 166 citations

, , +12

Synthesis and characterization of {2,6-bis[(dimethylamino)methyl]phenyl}tin(II) chloride and {2,6-bis[(dimethylamino)methyl]phenyl}(4-tolyl)tin(II), the first example of a mixed diaryltin(II) compound

Johann T. B. H. Jastrzebski, Paul A. van der Schaaf, Jaap Boersma et al. · Organometallics · 1989 · 108 citations

, , +7

Structure of Intramolecular Boron–Amine Complexes and Proposal of Tetrahedral Character for Correlation between Molecular Structure and Barrier to Dissociation of the N–B Bonds

Shinji Toyota, Michinori Ōki · Bulletin of the Chemical Society of Japan · 1992 · 103 citations

, , +14