Journal of the American Chemical Society · 2011 · 941 citations · 28 references
Natural SciencesMaterials EngineeringMaterials ScienceElectronic MaterialsPolymer ChemistryPolymer MaterialsLight-emitting DiodesOrganic SemiconductorsPhotovoltaic DevicesPhotovoltaic MaterialsQuantum DotsSolar CellsConjugated PolymersGrapheneGraphene Quantum DotsOrganic Light-emitting DiodesOrganic Photovoltaic CellsOrganic PhotovoltaicsOrganic Solar CellsPhotovoltaic Efficiency
Recent research in organic photovoltaic (OPV) is largely focused on developing low cost OPV materials such as graphene. However, graphene sheets (GSs) blended conjugated polymers are known to show inferior OPV characteristics as compared to fullerene adduct blended with conjugated polymer. Here, we demonstrate that graphene quantum dots blended with regioregular poly(3-hexylthiophene-2,5-diyl) or poly(2-methoxy-5-(2-ethylhexyloxy)-1,4phenylenevinylene) polymer results in a significant improvement in the OPV characteristics as compared to GSs blended conjugated polymers. This work has implications for inexpensive and efficient solar cells as well as organic light emitting diodes.
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