High-yield preparation of [2]rotaxanes based on the bis(m-phenylene)-32-crown-10-based cryptand/paraquat derivative recognition motif

Abstract

Based on the complexation between bis(m-phenylene)-32-crown-10-based cryptands and a paraquat derivative, two [2]rotaxanes were synthesized by using a threading-followed-by-stoppering method. Due to the strong associations between the cryptands and the paraquat derivative, high yields were achieved even in dilute solution.