Journal of The Electrochemical Society · 1992 · 73 citations · 0 references
Natural SciencesMaterials EngineeringMaterials ScienceCeramic MaterialsElectronic MaterialsSurface ScienceEtching ProcessesLaser Surface ProcessingOxide SemiconductorsPhotoelectrochemical MaterialsPhotoelectrochemistrySemiconductor Device MaterialsAnodic OxidationCeramic EtchingDevice FabricationEtch MechanismsEtchingSilicon Carbide (Sic) MaterialsSilicon EtchingSurface Etching
In this paper a nonthermal photoelectrochemical etching technique for is reported. The measured etch rates of 1–100 μm/min in this process are much faster than other etching methods currently available for this material. UV radiation is necessary for efficient photogeneration of holes near the surface. These holes are transported in the presence of an external bias to the semiconductor/liquid interface, where dissolution occurs through the anodic oxidation of the and the removal of the oxide by F− ions present in the electrolyte. The electrochemistry of and the etching process variables are discussed.