Nonlinear excited state absorption in cadmium texaphyrin solution

Abstract

Nonlinear absorption at 532 nm in a cadmium texaphyrin solution has been studied using 8 ns and 23 ps laser pulses. The experiments show that reverse saturable absorption occurs in the nanosecond case. For picosecond pulses, reverse saturable absorption occurs only at low fluences, and the transmission increases with increasing incident fluence at high fluences. A six-level model is presented to explain these nonlinear absorption effects. Several photophysical parameters for cadmium texaphyrin, such as absorption cross sections at 532 nm and lifetimes, have been evaluated by theoretical simulations of the experimental results.