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CROSSED ALDOL REACTION MEDIATED BY DIETHYLALUMINUM 2,2,6,6-TETRAMETHYLPIPERIDIDE (DATMP)
26
Citations
7
References
1979
Year
Title Aluminum AmideAldo-keto ReductaseCarbonyl MoietyOrganic ChemistryStereoselective SynthesisPharmacologyAsymmetric CatalysisT-butyl AcetateEnantioselective Synthesis
Abstract An efficient way of producing organoaluminum enolates of t-butyl acetate and of ketones is based on the title aluminum amide. Subsequent addition to a carbonyl moiety of various substrates affords the desired aldol adducts in fair to excellent yields.
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