Concepedia

The cationic cluster Grignard [{MgCl(thf)<sub>2</sub>}<sub>3</sub>(μ<sub>3</sub>-C<sub>3</sub>H<sub>5</sub>)<sub>2</sub>]<sup>+</sup>

Richard A. Layfield, Thomas H. Bullock, Felipe Garcı́a, Simon M. Humphrey, Peter Schüler

Chemical Communications · 2006 · 19 citations · 15 references

DOI

Concepts

Abstract

The synthesis and structure of [{MgCl(thf)2}3(mu3-C3H5)2]2[Mg(C3H5)4], which contains both a cationic cluster Grignard and a tetraorganomagnesiate dianion, are reported.

References

15

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<sup>25</sup>Mg‐NMR: A Method for the Characterization of Organomagnesium Compounds, their Complexes, and Schlenk Equilibria

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The First Alkaline Earth Metal Complex Containing a μ-η1:η1 Allyl Ligand: Structure of [{HC[C(tBu)NC6H3(CHMe2)2]2Mg(C3H5)}6] The financial support of the UK EPSRC (S.T.L., S.P.) and The Royal Society (C.A.M.) is gratefully acknowledged.

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