Inorganic Chemistry · 2008 · 92 citations · 44 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMaterials ChemistryPolymer ChemistryCluster ChemistryCoordination ChemistryCoordination PolymersInorganic SynthesisMetal-ligand BondingTransition Metal ComplexesCoordination Polymer SynthesisMetal CoordinationMetal Ion CoordinationMetal Ligand CoordinationMetal-ligand Coordination PolymersMetal-organic FrameworksMixed-metal Coordination PolymersPorous Coordination Polymers
The designed synthesis of heterobimetallic microporous coordination polymers (MCPs) is reported by a strategy employing the selective replacement of a single metal in homometallic MCPs with two unique metal coordination environments: octahedral and tetrahedral. This strategy is successful in the preparation of six mixed-metal MCPs, where Co/Zn and Ni/Zn versions of MOF-4, MOF-39, and a Zn-BTEC MCP are reported.
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Jaheon Kim, Banglin Chen, Theresa M. Reineke et al. · Journal of the American Chemical Society · 2001 · 831 citations