The Journal of Organic Chemistry · 2001 · 214 citations · 33 references
Natural SciencesChemistryCatalysisFunctional MaterialsInorganic ChemistryCatalyst CharacterizationCatalyst PreparationCatalyst SynthesisCatalytic MaterialsOxidation ReactionsSupported CatalystsAlcohol OxidationOxidationRecyclable MaterialsSilica SupportsSilica Surface FunctionalizationSilicate ChemistrySupported Catalyst PreparationSupported Oxidation Catalysts
The application of silica-supported TEMPO as a recyclable catalyst in the Anelli oxidation of alcohols is reported. The catalyst is easily obtained in a one-step reductive amination procedure starting from a commercially available aminopropyl-functionalized silica. Details of the synthesis of the supported catalyst and its analysis by MAS NMR are presented. Various alcohol oxidations according to the Anelli protocol have been carried out and the stability of the applied silica-supported TEMPO has been studied.
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Arné Dijksman, Arturo Marino-González, Antoni Mairata i Payeras et al. · Journal of the American Chemical Society · 2001 · 533 citations