Hexacyclo[10,3,1,02,10,,03,7,06,15,09,14]hexadecane; an ethanocongressane - Concepedia

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Hexacyclo[10,3,1,02,10,,03,7,06,15,09,14]hexadecane; an ethanocongressane

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1970

Year

Sowmya Rao, M. Sundaralingam, Eiji Ōsawa, E. Wiskott, P. VON R. SCHLEYER

Journal of the Chemical Society D Chemical Communications

Aluminium Halide RearrangementInorganic ChemistryMaterials ScienceEngineeringHeterocyclicDifferent Cyclo-octatetraene DimersStructure ElucidationX-ray AnalysisOrganic ChemistryMain Group ChemistryChemistryHeterocycle Chemistry

Abstract

The structure of a hydrocarbon, m.p. 110–111·5°, obtained from two different cyclo-octatetraene dimers (V) and (VI) by hydrogenation followed by aluminium halide rearrangement has been determined by X-ray analysis to be an ethanocongressane, hexacyclo[10,3,1,02,10,03,7,06,15,09,14]hexadecane (III).