Concepedia

An improved asymmetric epoxidation of allyl alcohols using titanium-pillared montmorillonite as a heterogeneous catalyst

B. M. Choudary, V. L. K. Valli, A. D. PRASAD

Journal of the Chemical Society Chemical Communications · 1990 · 64 citations · 6 references

DOI

Concepts

Abstract

A simple and convenient procedure for the catalytic asymmetric epoxidation of primary allyl alcohols with high enantiomeric purities and good yields using a hetereogeneous titanium-pillared montmorillonite catalyst is demonstrated.

References

6

Catalytic asymmetric epoxidation and kinetic resolution: modified procedures including in situ derivatization

Yun Gao, Janice M. Klunder, Robert M. Hanson et al. · Journal of the American Chemical Society · 1987 · 1.9K citations

, , +15

Asymmetric epoxidation provides shortest routes to four chiral epoxy alcohols which are key intermediates in syntheses of methymycin, erythromycin, leukotriene C-1, and disparlure

Bryant E. Rossiter, Tsutomu Katsuki, K. Barry Sharpless · Journal of the American Chemical Society · 1981 · 333 citations

, , +7

Synthesis and Properties of Titanium Oxide Cross-Linked Montmorillonite

Johan Sterte · Clays and Clay Minerals · 1986 · 312 citations

, , +11

Preparation and properties of titania pillared clay

Shōji Yamanaka, T. Nishihara, Makoto Hattori et al. · Materials Chemistry and Physics · 1987 · 194 citations

, , +6

Asymmetric epoxidation of allyl alcohol: efficient routes to homochiral .beta.-adrenergic blocking agents

Janice M. Klunder, Soo Y. Ko, K. Barry Sharpless · The Journal of Organic Chemistry · 1986 · 180 citations

, , +8