Concepedia

FORMATION OF α-TRICHLOROSTANNYL KETONES IN THE REACTION OF STANNIC CHLORIDE WITH ENOL SILYL ETHERS

Eiichi Nakamura, Isao Kuwajima

Chemistry Letters · 1983 · 20 citations · 5 references

DOI

Concepts

Abstract

Abstract The enol silyl ethers of ketones reacted with SnCl4 to give α-trichlorostannyl ketones in moderate to good yields, and their structures were determined by chemical and spectral means. The reaction mechanism is also discussed.

References

5

Generation, nuclear magnetic resonance spectra, and alkylation of enolates from trialkylsilyl enol ethers

Gilbert Stork, Paul F. Hudrlik · Journal of the American Chemical Society · 1968 · 183 citations

, , +6

Chemistry of carbanions. XXII. C- vs. O-acylation of metal enolates

Herbert O. House, Robert A. Auerbach, Martin Gall et al. · The Journal of Organic Chemistry · 1973 · 141 citations

, , +5

The metal effect on aldol type stereoselection. Erythro-selective condensations with aldehydes via .alpha.-mercurio ketones

Yoshinori Yamamoto, Kazuhiro Maruyama · Journal of the American Chemical Society · 1982 · 48 citations

, , +8

Stereo- and regio-controlled aldol synthesis

Isao Kuwajima, Masahiro Kato, A. MORI · Tetrahedron Letters · 1980 · 36 citations

, , +8

Regiochemical aspects in the reaction of 2,3,5-tri-o-benzoyl-d-ribofuranosyl

Yayoi S. Yokoyma, M. R. H. ELMOGHAYAR, Isao Kuwajima · Tetrahedron Letters · 1982 · 25 citations

, , +4