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Synthese und Kristallstruktur von [LiCl · 2THF]<sub>2</sub> / Synthesis and Crystal Structure of [LiCl · 2THF]<sub>2</sub>
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1991
Year
Materials ScienceInorganic ChemistryLithiated CatecholCrystal StructureEngineeringLi-ion Battery MaterialsCoordination ComplexStructure ElucidationOrganometallic CatalysisDistorted TetrahedronChemistryCrystallographyCrystal Structure DesignInorganic SynthesisLithium ChlorideInorganic Compound
The reaction of lithiated catechol ligands with W (0)Cl 4 produces LiCl as a side product. The lithium chloride from this reaction crystallizes as (THF) 2 Li(μ-Cl)-,Li(THF) 2 . The X -ray analysis shows lithium in the center of a distorted tetrahedron made up from two THF molecules and two bridging chlorides with d(Li-Cl) = 2.342(3) and 2.308(3)Å.