Publication | Closed Access
Shape Selective Epoxidation of Alkenes Catalyzed by Polyoxometalate-Intercalated Hydrotalcite
81
Citations
9
References
1992
Year
Materials ScienceChemical EngineeringSignificant Shape SelectivityHydrotalcite-free CatalystsEngineeringAlkene MetathesisHeterogeneous CatalysisOrganic ChemistryCatalysisHomogeneous CatalysisChemistryCatalyst PreparationShape Selective EpoxidationCatalytic SynthesisAbstract Hydrotalcite
Abstract Hydrotalcite pillared by polyoxometalates of Mo and W catalyzed epoxidation of alkenes with H2O2 with significant shape selectivity; epoxidation of 2-hexene was favored than that of cyclohexene. The subsequent hydrolysis of epoxides to form diols was retarded compared to hydrotalcite-free catalysts.
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