Chemical Communications · 2013 · 15 citations · 25 references
EngineeringRedox-triggered Structural RearrangementChemistryInorganic MaterialInorganic CompoundRedox ChemistryBiophysicsMaterials ScienceInorganic ChemistryOxide HeterostructuresMetal Oxide FrameworkCluster ScienceCrystallographyInorganic SynthesisNew TungstatoiodateSelf-assemblyMass SpectrometryCluster ChemistryMedicine
The new tungstatoiodate, α-[H5W18O59(IO3)](6-), containing I(V)O3(-) within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)](6-) by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I-O covalent bonds are broken.
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Towards Polyoxometalate‐Integrated Nanosystems
De‐Liang Long, Leroy Cronin · Chemistry - A European Journal · 2006 · 231 citations