Makromolekulare Chemie Macromolecular Symposia · 1992 · 13 citations · 9 references
Natural SciencesChemistryOrganic ChemistryPolymer ChemistryPolymer SynthesisPolymerization ChemistryPolymerization KineticsPolymerization ProcessesPolymerization Mechanism AnalysisPolymerization MechanismsPolymerization Of Vinyl MonomersVinyl Polymerization
Abstract The lecture reviews recent studies on vinyl and vinylidene compounds, chiefly alkyl cyanoacrylates. It emphasizes the kinetics, especially the distinctive SINT (slow‐initiation‐no‐termination) pattern, and the composite mechanism of initiation by tertiary amines. The need for corroboration of interpretations, clarification of ambiguities and extensions is emphasized.
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