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Enantioselective conjugate addition of diethylzinc to enones catalyzed by a copper complex of chiral aryl diphosphite
99
Citations
8
References
1999
Year
EngineeringChiral Aryl DiphosphiteCopper Complex1,4-Conjugate AdditionEnantioselective Conjugate AdditionOrganic ChemistryOrganometallic CatalysisCatalysisSynthetic ChemistryChemistryStereoselective SynthesisAsymmetric CatalysisChiral ArylEnantioselective SynthesisBiomolecular Engineering
The 1,4-conjugate addition of diethylzinc to cyclohex-2-enone and cyclopent-2-enone catalyzed by a copper complex of a chiral aryl diphosphite gave the desired products with 90.2 and 76.6% ee respectively.
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