New Organic Nonlinear Optical Polyene Crystals and Their Unusual Phase Transitions

Abstract

Abstract A series of new nonlinear optical chromophores based on configurationally locked polyenes (CLPs) with chiral pyrrolidine donors are synthesized. All CLP derivatives exhibit high thermal stability with decomposition temperatures T d at least > 270 °C. Acentric single crystals of enantiopure D ‐ and L ‐prolinol‐based chromophores with a monoclinic space group P 2 1 exhibit a macroscopic second‐order nonlinearity that is twice as large than that of analogous dimethylamino‐based crystal. This is attributed to a strong hydrogen‐bonded polar polymer‐like chain built by these molecules, which is aligned along the polar crystallographic b ‐axis. Five α‐phase CLP crystals with different donors grown from solution exhibit a reversible or irreversible thermally induced structural phase transition to a β‐phase. These phase transitions are unusual, changing the crystal symmetry from higher to lower at increasing temperatures, for example, from centrosymmetric to non‐centrosymmetric, enhancing their macroscopic second‐order nonlinear optical properties.