Journal of Materials Chemistry · 2012 · 148 citations · 37 references
Natural SciencesMaterials EngineeringMaterials ScienceComputational Materials ScienceMaterials ChemistrySolid-state ChemistryCrystal EngineeringNanomaterials For Energy StorageNanoporous MaterialsNanostructured Energy MaterialsPore Structure AnalysisPorous MaterialsCovalent Organic FrameworksCrystalline StructureGas StorageGas Storage MaterialsMesoporous MaterialsPore ArchitectureSolvothermal SynthesisSurface Area
An undulated two-dimensional CTC-based covalent organic framework, CTC-COF, was synthesized through solvothermal reaction for the first time. This mesoporous material stacks in an eclipsed mode in the microcrystalline state. CTC-COF has a surface area of 1710 m2 g−1, with a pore width of 2.26 nm calculated by the NL-DFT modelling. The bowl-shaped core unit led to a larger surface area than its analogue, COF-5 constructed by planar subunits. This material has higher low pressure hydrogen uptake than other 2D COFs with similar structures, and even close to the 3D COF materials.
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Hydrogen-storage materials for mobile applications
L. Schlapbach, Andreas Züttel · Nature · 2001 · 8.7K citations · Full text
Natural Sciences, Materials Engineering, Materials Science +12
Porous, Crystalline, Covalent Organic Frameworks
Adrien P. Côté, Annabelle I. Benin, N.W. Ockwig et al. · Science · 2005 · 8.1K citations