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A Zwitterionic Palladium(II) η<sup>3</sup>-Boratoxypentadienyl Complex: Cooperative Activation of Dibenzylideneacetone between Palladium and a Phosphine/Thioether/Borane Ligand
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Citations
36
References
2006
Year
Inorganic ChemistryChemical EngineeringZwitterionic PalladiumLewis Acidic BoraneEngineeringBiochemistryCooperative ActivationPhosphine/thioether/borane LigandNatural SciencesCoordination ComplexOrganometallic CatalysisMolecular ComplexChemistryLate Transition MetalFree Phosphine/thioether/borane LigandInorganic SynthesisInorganic Compound
A free phosphine/thioether/borane ligand (5) suitable to position a Lewis acidic borane in close proximity to a coordinated late transition metal has been prepared. Reaction with 0.5 [Pd2(dba)3] gave a zwitterionic palladium(II) η3-boratoxypentadienyl complex with the empirical formula [Pd(dba)(5)].
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