An efficient route to 3-deoxy-d-manno-2-octulosonic acid (KDO) derivatives via a 1,4-cyclic sulfate approach

Vicinal diol cyclic sulfates. Like epoxides only more reactive

Yun Gao, K. Barry Sharpless · Journal of the American Chemical Society · 1988 · 542 citations

Natural Sciences, Chemistry, Analytical Toxicology +5

Cyclic sulfates containing acid-sensitive groups and chemoselective hydrolysis of sulfate esters

B. Moon Kim, K. Barry Sharpless · Tetrahedron Letters · 1989 · 190 citations

Life Sciences, Biochemistry, Chemistry +8

Stereoselective total syntheses of the naturally occurring enantiomers of N-acetylneuraminic acid and 3-deoxy-D-manno-2-octulosonic acid. A new and stereospecific approach to sialo and 3-deoxy-D-manno-2-octulosonic acid conjugates

Samuel J. Danishefsky, Michael P. DeNinno, Shu Hui. Chen · Journal of the American Chemical Society · 1988 · 141 citations

Natural Sciences, Biochemistry, Chemistry +9

One pot synthesis of homochiral aziridines and aminoalcohols from homochiral 1,2-cyclic sulfates

Braj B. Lohray, Yun Gao, K. Barry Sharpless · Tetrahedron Letters · 1989 · 136 citations

Natural Sciences, Chemistry, Medicinal Chemistry +10

Structural elucidation of the 3-deoxy-D-manno-octulosonic acid containing meningococcal 29-e capsular polysaccharide antigen using carbon-13 nuclear magnetic resonance

Apurba K. Bhattacharjee, Harold J. Jennings, C. P. Kenny · Biochemistry · 1978 · 116 citations

Life Sciences, Biochemistry, Microbiology +16