Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals · 2001 · 20 citations · 4 references
Natural SciencesChemistryPhysicsOrganic ChemistryPhysical ChemistrySupramolecular ChemistryCrystal ChemistryCrystallization ProcessesCrystallographyLiquid Crystal MaterialsLiquid CrystalsMolecular SymmetryChiral Supramolecular MaterialsChiral ThermodynamicsCholesteric Liquid CrystalsCholesteric PhaseLiquid Crystal Phase BehaviorLiquid Crystal Supramolecular MaterialsMolecular Structure DeterminationTemperature Dependence
Abstract In this work, some of the most important characteristics of chiral compounds as components of the liquid crystal (LC) systems are discussed. These characteristics are the helical twisting power of chiral dopants (CDs) in the induced cholesteric (N*) mesophases, the temperature dependence of the induced helical pitch (P) quantified by the dP/dT parameter and the influence of the CDs on the N* mesophase thermal stability characterized by the dTiso /dC parameter. The molecular structure influence on them for several systematic series of the N-arylidene derivatives of (S)-1-phenyl- and (S)-1-benzylethylamines as well as the chiral diastereomeric 2-arylidene-p-menthane-3-ones is considered.
4
Molecular structure and the properties of liquid crystals
Journal of the Franklin Institute · 1962 · 927 citations
Natural Sciences, Chemistry, Physics +14